Styrene acrylonitrile resin, known as SAN, is a copolymer plastic consisting of styrene and acrylonitrile. Due to its superior thermal resistance, it is widely used in place of polystyrene. By weight the relative composition is usually 70-80% styrene and 20-30% acrylonitrile. Mechanical properties and chemical resistance of SAN can be improved with a larger acrylonitrile content, but the compromise is a yellow tint to the normally transparent plastic. Product from this plastics family includes food containers, water bottles, kitchenware, computer products, packaging material, battery cases and plastic optical fibers. Styrene gives the plastic a nice glossy finish. Styrene revenue is projected to increase at a compound annual growth rate (CAGR) of over 9% from 2019 to 2025, according to the Global Newswire network. They report an increased demand in the manufacture of various products, using acrylonitrile butadiene styrene (ABS), expanded polystyrene, and polystyrene as the contributing factors.
Getting the correct blend of copolymers to achieve the desired physical properties can be a challenging task for process engineers in the polymer industry. Near-infrared (NIR) spectroscopy is a convenient and cost-effective tool for monitoring reaction processes in situ to ensure that the correct chemical ratios, average molecular weight, and physical properties are within specifications.
When transparency is a concern, the process engineer has several options. If polystyrene’s mechanical properties are insufficient, the process engineer can tailor a specific formulation of styrene-acrylonitrile copolymers or SANs (Figures 1 and 2). These copolymers typically contain between 20–30% acrylonitrile. Due to the polar structure of acrylonitrile, SANs copolymers have better resistance to breakdown in hydrocarbon streams than polystyrene. SAN copolymers also have a higher softening point, rigidity, and impact strength, yet maintain their transparency.
Leave a Reply